Top 5 Ways to Maximize XP Gain in Starfield
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Scanning and surveying planets is a great way to farm XP early on in Starfield. Gas giants can be scanned automatically.
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Hunting dangerous alien creatures gives a lot of XP. Polvo is a great early hunting spot with herds of geophages and solitary bonemanes.
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Faction missions are a good repeatable XP source mid-game. Crimson Fleet and Ryujin Industries give lucrative missions.
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Tau Ceti VIII-b's forests have giant crickets that give huge XP boosts when defeated. It's a top mid-game hunting ground.
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Late-game, fight pirate ships at The Key or zealot ships in Serpentis. Bardeen III has profitable hunting with hornfaces that drop rare resources.